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Zero-Boil-Off Hydrogen Densification System

 

Hello, my name is Jong Baik.  At the Florida Solar Energy Center we are researching processes for increasing the density of cryogenic propellants for launch vehicle applications. This work is supported by NASA Glenn Research Center.

Technologies that provide for the densification, conditioning, transfer and storage of cryogenic propellants can reduce gross lift-off weight of a launch vehicle by up to 20% or increase its payload capacity. By using densified propellants, we can expect reduced external tank volumes, decreased vapor pressures, and increased enthalpy gain before boil off.  NASA Kennedy Space Center has years of experience handling cryogenic propellants, but all with saturated liquids.  This work focuses on using existing cryogenic technology to densify hydrogen, and developing a test bed where densified propellant handling techniques can be researched.  Florida Solar Energy Center and NASA Kennedy Space Center researchers designed, and a contractor fabricated our hydrogen densification system. Following is a short description of the densification system components.  

 

The hydrogen densification system consists of cryostat, cryocooler with helium compressor, vacuum pump system, gas and liquid cryogen supply system and data acquisition system.

 

The cryocooler constitutes the heart of the hydrogen densification system. Cryomech AL-330 single stage Gifford-McMahon cryocooler was selected and installed on the top of the densified hydrogen storage tank.  It has an expected cooling capacity of 40W at 20K and 25W at 15K. The cryocooler is integrated into the cryostat Dewar neck.

The water-cooled type helium compressor uses 7kW of power and provides 300 psi of gas to the cryocooler.

 

The double-walled cryostat has been designed to store 150 liters of densified hydrogen in its the stainless steel tank, with additional ullage space.  It is 20” in diameter and 40” in height, with multi-layer insulation and high vacuum space between inner tank and outer jacket.

 

To minimize convective heat transfer between inner tank and outer jacket, a combination of mechanical and turbo molecular vacuum pumps generates 10-6 torr of high vacuum.  Total loss including radiation, conduction through the support structure and instrumentation lines is less than 8.3W at 15K.

 

The entire assembly is designed to be easily modified, if needed, with flanged connections on the cryocooler interface and the outer jacket.

 

Since the cold head of the cryocooler is not long enough to reach the bottom of the storage tank, the heat pipe is used.

The heat pipe is located at the bottom of the cold head and extends the cryocooler cold head to the bottom of the inner vessel. It is 3” in diameter and 27” in length. This pipe uses hydrogen gas as working fluid.

 

Three silicon diode temperature sensors are installed on the cryocooler cold head, upstream and downstream of the heat pipe.  From our preliminary performance tests of the heat pipe using nitrogen, the maximum temperature difference between the cold head and the bottom end of the heat pipe was less than 1.5K. 

 

A gas supply line is wrapped around the bottom of the heat pipe so that supplied gas can be precooled, liquefied and densified at heat pipe temperature. 

 

Also, more than 2000 pieces of thin copper braids are attached to the bottom of the heat pipe to increase the contact surface area between heat pipe and fluids.

 

One capacitance-type liquid level gauge is installed to measure liquid level in the storage tank.

 

Five calibrated silicon diode sensors are installed on a 30” long fiber glass tube along the vertical axis of the storage tank to gauge liquid level in the tank.

 

A pressure buildup unit controls internal pressure by evaporation of stored liquid without any vent loss.

 

The pressure buildup unit consists of a cryogenic valve, a pressure regulator and evaporation coils at the bottom of cryostat.

 

Opening the pressure buildup valve allows stored cryogenic liquid to be evaporated in the pressure buildup coil by exchanging heat with ambient temperature and an increase in pressure of storage tank without imposing any external pressure. 

 

On the top flange, a vacuum-jacketed cryogenic liquid transfer line supplies cryogen to the storage tank or drains liquid out of the storage tank.

 

Using an additional gas supply line and a pressure buildup unit, we can easily transfer cryogenic liquid into or out of the storage tank.

 

Adjustable relief valve, rupture disk and manual venting valve are installed in the gas supply line, pressure build up coil and manual vent for safety.

 

In this densification system, various sensors are installed to study the thermophysical behavior of densified fluid.

 

Three pressure transducers measure the inner storage tank, annular vacuum space and heat pipe pressure.

 

Low and high vacuum gauges depict the pressures of the vacuum pump.

 

Two mass flow meters are installed at gas supply and vent lines measure the rate of liquefaction and heat leak. 

 

Eight temperature sensors measure the liquid level, cryocooler cold head temperature and heat pipe temperatures.

 

Signals from these instruments are sent to National Instrument field point data acquisition modules.

 

Labview 7 Real-time module performs all the data processing, display and storage of the data on a PC. All data acquisition modules can be monitored and controlled by intranet and internet from any remote location.

 

Researchers at the Florida Solar Energy Center and NASA Kennedy Space Center are collaborating on a test bed designed to gain operational experience in handling densified hydrogen.  This test bed has the capability to refrigerate, liquefy, densify and store hydrogen to temperatures near 15K. In preliminary densification tests, the G-M cryocooler has liquefied room temperature nitrogen gas to a 65K densified LN2 at a rate of 15 gallons/day. The system has successfully demonstrated continuous zero-boil-off storage at 65K for several weeks, requiring less than 1 hour a day of cryocooler operation. With our continued work in this area, we expect the hydrogen liquefaction and densification rates at 15K to be 1.2 gallons per day without liquid nitrogen pre-cooling, and 4.4 gallons per day with liquid nitrogen pre-cooling from room temperature gas. This excludes the energy release from the ortho-para hydrogen conversion process.  Our next step is to use hydrogen and demonstrate its liquefaction, densification and storage technologies.

 

Thank you for your attention.


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